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History of Stainless Steel

Date:2025/3/24 14:37:54
世界不锈钢发展简史
   商用不锈钢牌号于1912年前后诞生,而这建立在早期人类工业发展和众多伟人研究贡献的基础之上,如铁-铬合金、铁-铬-镍合金等合金钢的研究与发展,马氏体、铁素体、奥氏体金相组织的研究,耐腐蚀性能(钝化)的发现……
   不锈钢在生产工艺、技术装备、品种牌号开发与应用、产业规模等方面,不断在刷新历史。
   随着不锈钢应用的扩展,不锈钢商业牌号日益丰富,不锈钢的分类、统一编号与标准化也应运而生。其中,20世纪30年代美国钢铁学会(AISI)的不锈钢编号体系影响深远,被加拿大、巴西、南非、印度、英国、法国、日本、韩国等许多国家公认、采用或作为主要参考,如现在仍在使用的许多300系、400系牌号,AISI于20世纪60年代为高锰奥氏体不锈钢建立的200系牌号。
   1904年,法国L.B.Guillet教授发表一系列碳含量与现代不锈钢成分近似的铁铬合金研究论文,有些合金属于现代马氏体不锈钢和铁素体不锈钢,他还区分开了这些合金的基本金相特征。
   1906年,法国L.B.Guillet教授发表铁-铬-镍奥氏体合金的研究论文,合金化学成分与奥氏体不锈钢相似。
   1908年,德国的Philip Monnartz研究了碳含量对高铬钢耐腐蚀性能的影响;1911年他发表研究论文,发现钢中铬含量接近12%时,钢的腐蚀速率急剧降低,从而揭示了铬钢不锈(钝化)的原因。
   1911年,法国Albert M. Portevin发表研究成果,列出的合金中包括含铬17.38%、碳0.12%的合金(即后来著名的铁素体不锈钢430)。
   1911年,美国通用电气公司试验室的Christian Dantsizen,为电灯泡用引线成功研发了含铬14-16%、碳0.07-0.15%的合金(著名铁素体不锈钢430的前期),并于1914年用于制造蒸汽透平机叶片。
   1912年,德国克虏伯(Krupp)钢厂研究试验室的Edurard Maurer、Benno Strauss研发的含铬20%、镍7%的V2A合金(奥氏体不锈钢304的初型)获得德国发明专利。
   1913年8月,被誉为“不锈钢之父”的英国Firth Brown实验室主任Harry Brearley冶炼出含铬12.86%、碳0.24%的钢(马氏体不锈钢420的雏形),后于1914年首次由英国谢菲尔德托马斯弗思父子公司用于生产不锈钢餐刀。
   1915年3月,托马斯弗思父子公司的美国子公司弗思思特林钢公司(Firth-sterling)成为美国首家不锈钢厂,为刀具厂生产近似420的马氏体不锈钢。
   1920年,山特维克钢公司开始生产不锈钢。
   1924年,英国Firth Brown实验室的William A. Hatfield通过改进“V2A”,发明304不锈钢(含铬18%、镍8%,简称“18-8”)。
   1927年,克虏伯生产的铬25-镍20合金(即后来的“310”不锈钢)获专利权。
   1927年,美国钢公司的Bain和Griffiths首先发现了双相组织。
   1929年,卢森堡的William J. Kroll发现沉淀硬化不锈钢。
   1930年,美国纽约克莱斯大厦成为世界首座大量使用不锈钢的建筑。其100英尺高顶部尖塔的装饰使用了48吨德国Nirosta20-7不锈钢。
   1931年,巴德制造公司制造出世界首架不锈钢飞机。后来该公司还申请了18-8不锈钢电阻点焊专利,并制造出不锈钢房车、客车、轨道车、拖车等。
   1933年,瑞典阿维斯塔铁厂首次研制出奥氏体+铁素体双相不锈钢453E和453S(相当于美国1940年代开发出第一代双相不锈钢AISI329)。
   1933年,美国钢铁学会(AISI)制定了铸造不锈钢编号方法。300系代表铁铬镍奥氏体不锈钢,400系代表铁素体和马氏体铁铬不锈钢……
   1942年,美国电子冶金公司宣布加入少量氮可以改善铬不锈钢和铬镍不锈钢的性能。
   1945年,美国Carnegie-Illinois钢公司冶炼第一炉商用沉淀硬化不锈钢“Stainless W”。
   1946年,美国R.Smithetal成功研制马氏体沉淀硬化不锈钢17-4PH。
   1948年,美国阿姆科公司(Armco Steel)成功开发17-4PH及半奥氏体沉淀硬化不锈钢17-7PH、PH15-7 Mo等。
   1951年,美国阿勒根尼•路德姆公司开发出201、201L以锰代镍奥氏体不锈钢,以应对朝鲜战争期间镍资源的短缺。
   1959年,德国标准化学会(DIN)建立了一套钢铁材料五位数编号系统,1.40×× - 1.46××数字系列,表示不锈钢,1.47×× - 1.49××数字系列表示耐热钢和高温材料。同时,还用化学符号与表示元素百分比的数字给每种合金命名。后来欧洲、国际标准化组织、俄罗斯、 中国等也采用了这种命名方法。
   1968年,世界首座AOD炉在美国Joslyn制造与供应公司的印第安纳州韦恩保厂建成。
   1977年,南非米德尔堡钢与合金公司成功炼出3Cr12铁素体-马氏体不锈钢……
    1996年,国际不锈钢论坛(ISSF)成立
   ……

A Brief History of the Development of Stainless Steel in China

In 1952, Taiyuan Iron and Steel and Fushun Special Steel refined stainless steel, ending the history of China's inability to produce stainless steel

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In December 1970, Taiyuan Iron and Steel produced cold-rolled stainless steel sheets

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In September 1983, the first domestically produced 18 ton argon oxygen external refining furnace (AOD) produced the first ultra-low carbon stainless steel at Taiyuan Iron and Steel.

In December 1985, the first domestically produced 1280mm vertical stainless steel slab continuous casting machine produced the first stainless steel slab in China at Taiyuan Iron and Steel.

In October 1986, China's first cold-rolled wide strip stainless steel bright annealing line was put into operation at Taiyuan Iron and Steel Seventh Rolling Plant.

In 1992, Taiyuan Iron and Steel's stainless steel composite plate production line, stainless steel small material production line, and wide stainless steel cold-rolled plate production line were successively put into operation.

In August 1994, Taiyuan Iron and Steel's 1594mm hot rolling project and 1000 ton fast forging machine were completed and put into operation.

At the end of 1995, Shanghai Tenth Iron and Steel Plant and American Allegheny Ludm Company established China's first joint venture stainless steel precision strip production enterprise - Shanghai Shida. The first phase of the project was laid in 1997 and put into operation in 1999.

In 1996, Baosteel and Nippon Steel jointly established Ningbo Baoxin, a stainless steel cold-rolled plate enterprise

In early 1997, the National Development and Reform Commission, the Economic and Trade Commission, and the Ministry of Metallurgy jointly established a stainless steel research group to conduct market research, and formulated China's "Ninth Five Year Plan" for the development of stainless steel and a long-term plan for 2010, encouraging state-owned enterprises to develop stainless steel and establishing a development layout of "Nanbao Beitai".

In 1997, Taiyuan Iron and Steel Corporation put into operation a new 20 roll Sendzimir cold rolling mill imported from France

In 1997, Zhangjiagang Pohang Stainless Steel Co., Ltd. (ZPSS), controlled by Pohang Iron and Steel, was established. The first phase of the cold rolling project started in April

In 1998, Baosteel and Germany's Krupp jointly established the stainless steel cold-rolled plate enterprise Shanghai Krupp Company (SKS)

In February 1998, the first national stainless steel industry organization in China, the Stainless Steel Branch of the China Special Steel Enterprise Association, was established in Beijing

In January 2001, Baosteel laid the foundation for its stainless steel project, and in June, the first pile was laid

In 2002, Taiyuan Iron and Steel completed the renovation of its 500000 ton stainless steel production system, with an annual production capacity of 1 million tons of stainless steel. China's first converter stainless steel was produced using a three-step process

In December 2002, Taiwan Ye Lian established Lianzhong (Guangzhou) Stainless Steel Co., Ltd. as a wholly-owned subsidiary in December 2001. The cold rolling mill, hot rolling mill, and steel mill were put into operation in 2004, 2006, and 2007 respectively

In 2002, China's apparent consumption of stainless steel surpassed that of the United States, ranking first in the world

In September 2004, Taiyuan Iron and Steel started construction on a new 1.5 million ton stainless steel project, which was completed in September 2006 with a production capacity of 3 million tons

In June 2005, Baosteel's stainless steel expansion project was completed, with a stainless steel production capacity of 1.5 million tons

In 2005, the expansion and renovation project of Taiyuan Iron and Steel's stainless steel cold-rolled sheet was completed, resulting in an annual production capacity of 900000 tons of cold-rolled sheet

In 2006, the first phase of the 200000 ton slab production line of Southwest Stainless Steel Company was put into operation

In July 2006, ZPSS's annual production of 600000 tons of hot rolling and steelmaking project was put into operation, becoming a comprehensive stainless steel production enterprise

In 2006, China's stainless steel production surpassed Japan and ranked first in the world

In August 2007, Baosteel's stainless steel cold rolling production line was completed and put into operation

In November 2007, the Jiugang Cold Rolled Stainless Steel Project was officially put into operation, becoming a comprehensive stainless steel production enterprise with consistent production methods

In March 2008, Qingtuo Group settled in Fu'an, Fujian

In May 2009, Beihai Chengde was established

In August 2009, the steelmaking production line of Dongfang Special Steel was officially put into operation

In August 2010, Jiangsu Delong Nickel Industry Co., Ltd. was established

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In November 2013, Zhongjin Metal was established

In October 2014, Ansteel reorganized Lianzhong (Guangzhou) Stainless Steel Co., Ltd

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In January 2018, Liugang acquired controlling stake in Zhongjin Metal

Before the reform and opening up, stainless steel, as a high-end product in steel materials, was mainly used in China's national defense, aerospace, petroleum, power, chemical and other industrial fields. It was mostly a necessary, urgent and cutting-edge field with strong corrosiveness or high temperature and other harsh environments. In 1978 and 1979, the demand for stainless steel was only around 100000 tons.

Around 1978, China's crude stainless steel production was about 90000 tons. The production process mainly involves a one-step electric arc furnace method without external refining. The vast majority of stainless steel products are 300 series austenitic steels, and before 1988, 1Cr18Ni9Ti (321) accounted for the vast majority of austenitic stainless steel products. There are only 23 stainless steel grades in the heavy 20-52 and heavy 21-52 standards, including 6 ferrites, 5 martensite, and the remaining 12 austenitic grades.

After the reform and opening up, the consumption of stainless steel in China has continuously expanded, and the scale of stainless steel consumption has been increasing, creating important market conditions for the development of China's stainless steel industry. The investment and construction in the fields of light and heavy industry have expanded the demand for stainless steel in industrial equipment, and the consumer sector has also expanded to include civilian consumer goods such as kitchenware, equipment for medical and transportation industries, and construction facilities such as municipal facilities and buildings. Since 2002, China has surpassed the United States and Japan to become the world's largest stainless steel consumer market.

With the significant increase in stainless steel consumption in China in the 1990s, the lack of quantity, variety, and quality in the domestic stainless steel industry became increasingly apparent, especially in cold-rolled sheet metal, which could not meet the needs of the market, resulting in a large number of imports and even a large amount of smuggling from 1995 to the end of the 20th century. In 2005, the import volume of stainless steel in China reached a historical high of over 3.13 million tons.

Driven by favorable market prospects and supported by reform and development policies, state-owned, private, and overseas capital actively invest in and develop the stainless steel industry. In early 1997, the National Development and Reform Commission, the Economic and Trade Commission, and the Ministry of Metallurgy jointly established a stainless steel research group to conduct market research, and formulated China's "Ninth Five Year Plan" for the development of stainless steel and a long-term plan for 2010, encouraging state-owned enterprises to develop stainless steel and establishing the development layout of "Nanbao Beitai". Since the founding of the People's Republic of China, state-owned special steel enterprises have long been the main force in domestic stainless steel production. At present, state-owned (holding) enterprises such as Taiyuan Iron and Steel, Baosteel, Jiuquan Iron and Steel, Ansteel, Beihai Chengde, and Liugang are still important components of China's stainless steel industry. Since the late 1980s, private stainless steel enterprises producing stainless steel bars, pipes, narrow strips, and other products have gradually emerged in areas such as Dainan in Xinghua, Lanshi in Foshan, Huzhou, Wenzhou, Jiaxing, and Ningbo in Zhejiang. At present, private enterprise Qingshan Industrial has become the world's largest enterprise in terms of stainless steel production capacity and output. Since the mid-1990s, foreign enterprises such as POSCO, Krupp, Nippon Steel and Allegheny Technology, as well as Taiwan funded enterprises such as Yilian, Formosa Plastics and Huaxin Lihua have also actively invested in the stainless steel industry in Chinese Mainland through joint ventures or sole proprietorships.

At present, China's stainless steel crude steel production ranks first in the world, accounting for over 50% of the total, reaching more than 26 million tons in 2018. Moreover, China has become a net exporter of stainless steel.

The three major technologies of the 20th century - external refining, continuous casting, and multi roll cold rolling - are now adopted in China's stainless steel industry. High end pipe production in enterprises such as Jiulite Material, Taiyuan Iron and Steel, Baosteel, and Great Wall Special Steel adopts hot extrusion technology, while Qingshan Industrial has innovatively developed a nickel iron and stainless steel integrated production process (RKEF+AOD dual method stainless steel smelting process) with significant impact

At present, China has a complete range of stainless steel varieties and specifications, including ultra thick, ultra wide, ultra-thin plates and strips, ultra large caliber seamless pipes, welded pipes, high-precision capillary tubes, etc. Such as "hand torn steel" (cold-rolled precision strip that can be ultra-thin to 0.02mm), ballpoint pen head steel, etc. In terms of stainless steel grades, the total number of grades included in the national standard for heat-resistant stainless steel grades (GB/T20878-2007) released in 2007 reached 143 (excluding the 21 grades that were outdated and eliminated). Among them, there are 18 ferritic grades, 38 martensitic grades, 66 austenitic grades, 11 duplex steel grades, and 10 precipitation hardening grades. In addition, many companies have successively developed new enterprise standards or group standard grades


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